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Application of the Collision Cell (CCT) in the ICP-MS Analytical System
120-125Views:722Our laboratory has seen a sharp rise in the number of requests for the analysis of smaller and smaller concentrations of elements from foods, plants, soil, organic fertiliser, irrigation and ground water, sewage, sewage sludge, raw material of food, as well as human and animal origin samples. From the above elements the inductively coupled plasma mass spectrometer is capable of analysing the smallest concentration of elements. Our method of analysis is to use our ICP-MS instrument, together with a ICP-MS with Collision Cell Technology (CCT). The CCT method has better detection limit, with 1-3 magnitudes, compared to the normal ICP-MS analytical method. The CCT has better detection limits mainly for the following elements in the periodical system: analysis of arsenic, selenium, germanium, vanadium and chromium. Additionally a collision cell can be applied for the analysis of silicium, sulphur, zink, copper, iron, calcium, magnesium and potassium in smaller concentrations.
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Element content analyses in the Institute for Food Sciences, Quality Assurance and Microbiology
203-207Views:387The role of chemical elements to ensure and promote our health is undisputed. Some of them are essential for plants, animals and human, others can cause diseases. The major source of mineral constituents is food, drinking water has a minor contribution to it, so the knowledge of elemental intake through food is crucial and needs continuous monitoring and by this way it promotes the food quality assurance and dietetics.
With the evolution of spectroscopic methods increasingly lower concentrations could be determined, so the elemental composition of a sample could be more precisely and fully described. Due to the results the gathered knowledge up to the present is supported and new observations can be done helping us to understand such complex systems as biological organisms are.
The quality of a food is determined by the full process of its production, consequently it starts with agricultural production so elemental-analysis usually cover the whole soil – plant – (animal) – food chain, by this way the „Fork-to-Farm” precept is true in elemental analysis field also.
The history of elemental analysis in the University of Debrecen, Centre for Agricultural and Applied Economic Sciences, Faculty of Agricultural and Food Sciences and Environmental Management, Institute of Food Processing, Quality Assurance and Microbiology goes back to 1980s when the so called Regional Measurement Central gave the background for research. The continuous deployment resulted in an obtain of an inductively coupled plasma atomic emission spectrometer (ICP-AES) in 1988, which extended the scope of examinations due to its excellent performance characteristics
compared to flame atom absorption (FAAS) and flame emission spectrometers (FES). The instrumental park retain up to date correlate to the developing analytical techniques due to acquiring a newer ICPAES in 1998 and an inductively coupled plasma mass spectrometer in 2004 – which sensitivity is three order of magnitude better compared to ICP-AES. The Institute supports the work with its own ICP-AES and ICP-MS since 2011. -
Determination of the validation parameters of inductively coupled plasma mass spectrometer (iCP-mS): response curve linearity in the case of arsenic and selenium
67-71Views:489In the field of elemental analysis inductively coupled plasma mass spectrometers (ICP-MS) have the best sensitivity that means the lowest limit of detection, subsequently their applicability for the detection of essential and toxic elements in foods and foodstuffs is prominent. For the most elements could be measured the detection limit is between μg kg-1 (ppb) and ng kg-1 (ppt) e.g. for arsenic and selenium.
Considering an analytical task (sample type, analytes and their concentration, pretreatment procedure etc.) the applicability of an analytical method is determined by its performance characteristics. The purpose of validation is to ensure that the method would be used fulfills the requirements of the given task. In this article we describes one of the performance characteristics, the linearity, and the whole validation procedure aims measurement of arsenic and selenium in foodstuffs by inductively coupled plasma mass spectrometer (Thermo XSeries I.); but because of the limited number of pages the results are demonstrated only for arsenic.
The linearity of calibration was evaluated in three concentration ranges (0.1–1 μg l-1; 1–10 μg l-1; 10–50 μg l-1), with nine line-fit possibilities (without weighting, weighting with absolute or relative deviation; with or without forcing the curve through blank or origin) and different methods (graphical examination, correlation coefficient, analysis of variance).
The best method to ensure the linearity of correspondence between signal and concentration was the ANOVA test. In view of calibrations it was found that the range of 10–50 μg l-1 could be regarded as linear with four line-fit possibilities, and was non-linear between 0.1–1 μg l-1 and 1–10 μg l-1.
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Parameter optimization of an inductively coupled plasma mass spectrometer for measuring arsenic and selenium
81-85Views:578In the last decades, an increased interest has evolved in arsenic and selenium. The aim is to understand the environmental, agricultural and biological roles of these elements. In the case of arsenic, the major reasons are the relatively high concentration of arsenic in marine biota (mg kg-1) and the arsenic contaminated drinking water bases of some Asian countries, as well as Hungary. The toxicity of higher level selenium content is also known; nevertheless, selenium is essential for several biological functions. Considering its essentialness, in our country, the insufficient selenium intake rate causes a lack of selenium. Measuring the concentrations of these elements provides crucial, but unsatisfactory information, as the speciation, i.e. the form of an element presented in a sample is also required.
In both cases, the most suitable method to determine concentration is inductively coupled plasma mass spectrometry (ICP-MS). Our objective was to optimize the variable parameters of the ICP-MS to attain the lowest (the best) detection limit. For this purpose, we investigated the effect of parameter change on net signal intensity and relative signal intensity. With the optimized parameter settings, the limits of detection for arsenic and selenium were determined, which are 0,032 ng dm-3 for arsenic, and 0,097 ng dm-3 for selenium. -
Selenium speciation analysis of selenium-enriched food sprouts
23-28Views:541In this present study, we prepared selenium-enriched pea and wheat sprouts. During our research we aimed not only to measure the total selenium content of the sprouts but to identify different selenium species.
Scientifical researches show why the analytical examination of different selenium (Se) species is necessary: consumption of all kind of Se-species is useful for a person who suffers in selenium deficit, while there is significant difference between effects of different Se-species on person, in whose body the Se-level is just satisfactory. Biological availability, capitalization, accumulation, toxicity of Se-species are different, but the main difference was manifested in the anti-cancer effect of selenium.
During our research selenium was used in form of sodium selenite and sodium selenate, the concentration of the solutions used for germination was 10 mg dm-3. Control treatment meant germination in distilled water. Total selenium content of sprout samples was measured after microwave digestion by inductively coupled plasma mass spectrometry (ICP-MS). Different extraction solvents were applied during sample preparation in order to separate different Se-species (0.1 M and 0.2 M HCl or 10 mM citric acid buffer). We wanted the following question to be answered: Which extraction solvent resulted the best extraction efficiency? Selenium speciation analysis of sprout sample extracts was performed by high performance liquid chromatography with anion exchange column, detection of selenium species was performed by ICP-MS.
Evaluating our experimental results we have been found that significant amount of selenium of inorganic forms used during germination transformed into organic selenium compounds. There was difference between the amount of Se-species in pea and wheat sprouts and selenium uptake and repartition of selenium species were depended on Se-form used during germination. In addition the chromatogram analysis made us clear as well, that the citric acid solvent proved to be the most effective extraction solvent during sample preparation int he view of organic Se species.
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Selenium-speciation experiments from soil samples by accept of ionchromatography-inductively coupled plasma mass spectrometry (IC-ICP-MS) method
106-111Views:659In these days, selenium is one of the most investigated microelements. It has an important proven role in many vital processes. Selenium deficiency can play a role in the contraction of many diseases (e.g. cancer, heart diseases, etc.) and in the aggravation of their clinical aspect directly or indirectly. In this paper, we study the soil samples of an outdoor experiment for the conversion of the inorganic selenium salt that was spread out in different doses. The danger of the wash-out effect was also investigated. Our experiments showed, that most of the inorganic selenite transforms to selenate form during the years, and in this selenate form it moves to the deeper layers of soil.
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The effect of collecting area on the element content of Hungarian acacia honeys
129-138Views:563Six macroelements and twelve microelements were identified in thirty-six Hungarian acacia honeys collected from ten counties by inductively coupled plasma optical emission spectrometry (ICP-OES) and inductively coupled plasma mass spectrometry (ICP-MS). One-Way ANOVA (LSD and Dunnett T3 test) and linear discriminant analysis (LDA) were used to determine the statistically verified differences among the honey samples with different geographical origin.
Significant differences were established among the samples from different counties in Na, P, S, Fe, Ni, Cu and Sr concentrations. Based on the macroelement content of honeys, the separation of samples with different geographical origin was not successful because the percent of correctly categorised cases was only 64.9%. However, examining the As, B, Ba, Cu, Fe Mn, Ni and Sr concentration, the separation of different groups was convincing since the percent of correctly classified cases was 97.2%. Thus, the examination of microelement concentration may be able to determine the geographical origin of acacia honeys.
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Effect of molybdenum treatment on uptake of plant and soil molybdenum content in a field experiment
117-122Views:583Molybdenum is not a well-known microelement, but being a constituent of several important cellular enzymes it is an essential microelement. Molybdenum occurs in all foods, but at very low levels. There does not appear to be any particular foods or types of foods, which in the absence of extrinsic factors, naturally have high levels of molybdenum. However, environmental pollution, from natural or anthropogenic sources, can lead to high level of the metal in plants.
Our study is based on the long-term field experiments of Nagyhörcsök, where different levels of soil contamination conditions are simulated. Soil and plant samples were collected from the experiment station to study the behaviour of molybdenum: total concentration, available concentration, leaching, transformation, uptake by and transport within the plants, accumulation in different organs, phytotoxicity and effects on the quantity and quality of the crop. In this work we present the results of maize and peas and the soil samples related to them.
According to our data molybdenum is leaching from the topsoil at a medium rate and it appears in the deeper layers. In the case of plant samples we found that molybdenum level in the straw is many times higher than that is in the grain, so molybdenum accumulates in the vegetative organs of the plant. The data also show differences in the molybdenum-uptake of cereals and Fabaceae (or Leguminosae). -
Toxic elemental content of Hungarian blaufränkisch wines
87-90Views:585Toxic elemental contents are one of the food safety risks in wines. Therefore International Organization of Vine and Wine (O.I.V.) defined the limit of some elements in it. Thirty Hungarian blaufränkisch wines were analysed by ICP-MS in order to determine the concentration of toxic elements. All wines are passed by the O.I.V limits to toxic element content (Cu, Zn, Cd, Pb) according to analysis. Copper is the only outlier in some samples, but they also did not overstep the limit. In the case of zinc the maximum is approximately fourth, in case of cadmium and lead the highest concentration is less than tenth and sixth of the O.I.V. limit, respectively.
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Comparison of the sample preparation methods worked out for the examination of the element content of wine
77-82Views:436The examination of the potentially toxic elements content of the wines is not easy task, because the most elements are in little concentration (mg kg-1 or μg kg-1) in the wine and the wines contain great amount of organic matrix. The efficient sample preparation is essential for the accurate determination of element content. The eim of our research was to determine which sample preparation method will be the most efficient in examination of wines with ICP technology. The examined wine sample was a 2008 Chardonnay from the Eger wine region. We did the sample preparation and analysis examination in University of Debrecen, Centre for Agricultural and Applied Economic Sciences, Institute of Food Science, Quality Assurance and Microbiology.
We did the analysis examinations with ICP- MS (inductively coupled plasma mass spectroscopy). We always did the sample preparations and the examinations in three times rehearsal. The applied sample preparation methods: dilution with distilled water, open digestion and microwave digestion.
We were able to measure B, Al, Mn, Fe and Zn with only dilution and open sample preparation. In the smaller quantity present Sr and Ba were measurable in the wine in the case of all three methods well. We were able to measure the Co with dilution and open digestion method, while Cr, Ni, and Te with only dilution method. In the case of arsenic we were not able to measure reliable result with dilution and open digestion method because of organic matrix and other components
(alcohols, monosaccharides, polysaccharides, polyalcohols and inorganic salts). On the whole we are able to say that in the case of certain elements (B, Mn, Fe, Zn, Sr, Ba) the open digestion and dilution sample preparation is applicable well, however, in the case of certain elements (As, Al, V, Cr, Se, Mo, Cd, Hg, Pb) we have to develop the methods. It may be development of one of the way, if we develop sample preparation methods to examined element specifically and not
to wine generally. -
Comparative analysis of sample preparation methods to determine the concentration of arsenic in soil- and plant-samples
167-170Views:478Arsenic contamination of the fields and groundwater is a global problem. Alföld is the most affected area in Hungary. Irrigation witharsenic contaminated water, and crop production on the contaminated soil can cause a food safety problem, because arsenic is easy taken up by the cell of the plant roots. To prevent this, very important to monitoring the arsenic content of soils and plants. Inductively coupled plasma mass spectrometry (ICP-MS) is a fast, easy method to determined the concentration of minerals in the case of plant and soil samples The analytical methods can give reliable, results if the analytical process, including the sample preparation method, is the best. The objective of this study was to compare 3 type of sample preparation method which was dry ashing, wet digestion in open system, and microwave digestion. As a result of our experiement shows the microwave digestion is the appropriate method to determined the arsenic content of soil samples. In the case of plant samples we can use wet digestion in open system or microwave digestion as a samle preparation method.
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Optimization of inductively coupled plasma mass spectrometer parameter’s to measuring arsenic and selenium
59-64Views:750In the last decades an increased interest has been evolved about arsenic and selenium. The aim is to understand the environmental, agricultural and biological role of the these elements. In case of arsenic the mayor reasons are the relatively high concentration of arsenic in marine biota (mg kg-1) and the arsenic contaminated drinking waterbases of some Asian countries besides Hungary. The toxicity of higher level selenium content is also known, nevertheless selenium is essential for some biological functions. Considering its esssentiality, in our country the insufficient selenium intake rate couse lack of selenium. Measuring the concentrations of these elements are cruital but not satisfactory information, but the speciation, that is the form of an element presented in a sample is also required.
In both cases the most suitable method to determine concentration is the inductively coupled plasma mass spectrimetry. My objective was to optimase the changeable parameters of the ICP-MS for reaching the lowest (the best) detection limit. For this porpuse I have investigated the effect of parameter change on nett signal intensity and relative signal intensity. With the optimased parameter settings the limit of detection for arsenic and selenium were determined, which are 0,032 ng cm-3 for arsenic, and 0,097 ng cm-3 for
selenium. -
Elemental content of propolis samples from Pest, Zala and Bács-Kiskun county (Hungary)
149-153Views:526The elemental content of 61 raw propolis samples from Pest, Zala and Bács-Kiskun county (Hungary) were analyzed by ICP-OES. The content of Al, B, Ca, Cu, Fe, K, Mg, Mn, Na, P, S, Sr and Zn were measured in the samples. Median is higher than mean in all cases based on the summarized results. It can be explained by the outliers, moreover it has a non-normal distribution. The concentrations are in an extremely wide range, the ratio of the maximum and minimum is under 10 in case of six elements, between 10 and 35.1 in the case of other six elements,and more than 300 in case of Zn. Significant differences are between counties only in the case of B, K and P based on ANOVA. Other elements have no significant differences. The following order can be set up based on the mean concentrations and the wide ranges: K≥Ca>P≥S≥Fe≥Mg≥Al>Zn≥Na>Mn≥B>Cu≥Sr. Moreover it can be established, that the measured concentrations are near the same or in some cases lower than in other publications.
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The effect of wool staple length on the mineral content using the same sheep feeding regime
97-100Views:635The wool of sheep is suitable to test the mineral supply; however, a number of factors could affect the results. The growth rate and length of staple can be very different according to season, physiological state and individual variation. These factors are likely to affect the quantity of minerals accumulated into the wool. Therefore, the purpose of this research was to examine whether there is a difference between the mineral content of wool nearly reached the full staple length and the freshly grown wool using the same feeding regime.
10 Tsigai pregnant sheep have been selected randomly from the same farm. Wool samples were obtained from the withers, side and quarter with bended scissors. Samples were mineralized using nitric acid and hydrogen peroxide using ultrasonic cleaning unit. P, Ca, Mg, Na, S, Cu,Se and Zn content were determined by ICP-OES. Statistical analyses were carried out by SAS (SAS Institute Inc., Cary, NC) GLM procedure.Differences between means were tested by Tukey test. Significantly lower Ca, Na, P, Zn values were found in case of intensively grown wool. Sampling location did not affect the mineral content. Herd mineral supply was adequate. Our results suggest that intensively grown wool samples have to be used for mineral analyses. -
Macro element contents of different genotype cows’ milk
27-31Views:585The level of mineral elements is important factor regarding the quality of milk. The aim of our research study was to determine the content of mineral elements in milk of Holstein, Jersey, Brown Swiss, Ayrshire, Norwegian-red, Swedish-red cows in the first stage of lactation. All cows were fed with the same type (composition) of feed and they were kept under the same condition. The concentration of macroelements (K, Na, Ca, P, Mg, S) in digested milk samples was determined by inductively coupled plasma optical emission spectrometry (ICP-OES).
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The effect of NPK treatments on the Cu and Fe content of winter wheat (Triticum aestivum L.)
31-34Views:545In this study the effect of N, P and K nutrients on the Cu and Fe content of winter wheat (Triticum aestivum L.) grains was investigated in a long-term fertilization experiment set up in Nagyhörcsök. Samples were also harvested from four experimental stations of the Hungarian national long-term fertilization trials. These are the following: Bicsérd, Iregszemcse, Karcag, and Putnok. Plant samples were collected in 2005 which was very wet. Our results from Nagyhörcsök were compared with the Cu and Fe content of samples which were harvested from control plots of other experimental stations. The Cu and Fe content of grain samples were measured using inductively coupled plasma mass spectrometer (ICP-MS) followed by digestion with HNO3-H2O2 solution. All data were subjected to ANOVA, and when significant differences (P<0.05) were detected, Duncan’s test was performed to allow separation of means.
The main conclusions are as follows: Cu and Fe content of wheat grains was higher and higher in every NPK treatments. Samples were harvested from the control plots of Iregszemcse and Bicsérd have higher Cu content than the treated samples from Nagyhörcsök.
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Investigation of the Quality of Winter Wheat in a Sulphur Fertilisation Experiment, 2001/2002
153-156Views:447We have started a small parcell and a factorial S fertilization experiment with winter wheat in the 2001/2002 cropping year to examine its effect on yield and quality. The scene of experiment was the Latokep Experimental Station of the DE ATC (calcareous chernozeem) in case of small parcell examination and the Agricultural Company of Felsőzsolca (brown forest soil) in case od factorial examination.
The protein and gluten content of the grain was investigated with PerCon Inframatic 9001 NIR Analyser, then we have measured these parameters with PerCon 8620 infra appliance. After the milling we measured the following parameters: glutenindex, farinographic parameters (farinographic index, water absorption capacity, dough development time, stability, softening, extension) and valorigraphic index.
Based on the results there’s no justified relation between the fertilization and the protein and gluten content. The valorigraphic index of the samples taken from Felsőzsolca factory characteristically increased as a result of the S-fertilization. In the small-parcell experiment the values of the water absorption capacity, the dough development time and the softening parameters from the valorigrphic parameters depended significantly from the mineral treatments. Signifikant quality improvement wasn’t experieced.
There was sampling in all of critical phenophase (…). The green plant samples were examined on element content with ICP-OES. These measurements are currently in progress. -
Relation of availability and barley uptake of some potentially toxic elements
7-10Views:213A small-plot microelement load field trial was set up on brown forest clay soil with eight elements (Al, As, Cd, Cr, Cu, Hg, Pb, Zn), on 3 levels each (0/30, 90, 270 kg element ha-1). The soil was treated with soluble salts of elements once at initiation (1994). In the seventh year of the experiment (2001) winter barley was the test plant. The total element content was determined in plant samples (shoot, straw, grain) after microwave digestion using cc.HNO3+cc.H2O2. The element composition of the prepared samples was determined using ICP-MS technique. In the experiment toxic effects of treatments and yield loss could not be observed. Zn and As contents in barely shoots were only moderately increased by increasing microelement loads. Effects of Cr, Cu, Hg, Pb and Al treatments could not be observed. On the other hand, Cd accumulation was significant in the shoot. Cd content was also increased both in straw and grain. Results of this experiment prove that Cd remains mobile in the soil-plant system for a long time. Its accumulation can be observed both in vegetative and reproductive parts of plants without toxic symptoms and yield loss.
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Investigating the above-ground biomass values of sweet potatoes (Ipomoea batatas)
35-39Views:400The role of sweet potato tubers in human nutrition is not new. The above-ground biomass of sweet potatoes is not used for nutritional purposes in most countries, but it has a high biological value. Therefore, the aim of the present study is to investigate the production of press fibre from above ground biomass by wet fractionation. Two sweet potato varieties (purple- and white-fleshed sweet potato) and two types of irrigation system were used: bubbling water flow system (BWS) and continuous water flow system (CWS). Glucan, xylan, arabinan were analysed by HPLC and elemental content was measured by ICP-OES. Our results show that the total carbohydrate content in the pressed fibre of the leaf blades (27.64–29.88 %w/w) is lower than in the stem with petiole (51.14–57.36 %w/w). No significant difference in glucan, xylan and arabinan content was observed in the leaf blade. In the stem with petiole, significant differences were observed for xylan and arabinan contents. For elemental content, generally higher values were measured in the leaf blade than in the stem with petiole. This information may be relevant for the selection of the appropriate variety and treatment, even for the production of functional food.
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The effect of genotype and the location of sampling on the mineral content of wool
157-160Views:716Mineral supplementation is very important in high producing farm animals. The estimation of exact mineral intake is very difficult in forage eating animals, like sheep. Accessing of long term mineral status seems to be possible using wool mineral analysis. However several factors can affect the results. Therefore, the aim of this study was to test the effect of breed and sampling location on the mineral content of sheep wool. 20 Dorper and 20 Tsigai sheep were chosen from the same farm. Samples were obtained from 3 locations (withers, side and quarter) and tested for 8 elements: Ca, Mg, Na, Co, Cu, P, S, Se , Zn. The samples were cleaned with ethyl alcohol from organic contamination, then after adding nitric acid were mineral analized using ultrasonic cleaning unit. The samples were analysed with ICP-OES (Perkin-Elmer, Optima 3300 DV). Statistical analyses were carried out by GLM procedure of SAS statistical analyses software. Differences between means were checked with Tukey-test. Significant breed differences were detected in the case of Mg, Na, S, Se in spite of the same feeding regime. The wool mineral content were within the reference range. The sampling location had no effect on the mineral content of wool.
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The effect of nickel-contamination, nitrogen-supply and liming on the chemical composition of perennial ryegrass (Lolium perenne L.)
85-92Views:222Plant-production is determined by many production-factors. Each of these factors became subject of research-works through the years, still we state, that studying their interaction is even more important. For studying these interactions we set up a potexperiment, within that the direct effect and the interactions of four factors was inspected: soil, nitrogen-supply, nickel-loading and liming. Experiments were carried out on two soil types with extremely different characters: one was a chernozem soil with good fertility and buffering capacity, the other was a shifting sand soil with low humus-content and buffering capacity. Nitrogensupply and liming was added on two levels, while nickel on three within 12 combinations on each soil types. Plant production was cut two times within the vegetation period. The amount of production and dry matter was weighted, fractured and their element-content was measured by an ICP-detector.
Ca-content on the shifting sand soil was determined by all three factors, however the interaction between nickel-loading and liming was also significant. Nitrogen and liming increased Cauptake, that is due to appropriate nutrient-supply and improvement of a better pH-value. On the chernozem soil nitrogen and CaCO3 also increased the Ca-content. This is caused by a better nutrient supply and a higher amount of available Ca-ions.
On the shifting sand soil nickel content was increasing parallel to higher nitrogen-dosages. In presence of higher nickelamount the nickel-content of plants was also increasing, still according to liming, this increment was different. On the chernozem soil nitrogen a nickel increased Ni-uptake. However, liming also had a positive effect on Ni-content, that can be explained by the high amount on colloids in the soil, the adsorption of Ni-ions on them and in presence of liming material the replacement of Ca-and Ni-ions.
The potassium-content on the shifting sand soil was different in each liming-combination. In combinations without nickel the potassium-content of limed and not limed combinations was on the same level. In not limed combinations by adding nickel potassiumcontent was increasing, while in limed combinations no change was observed. On the chernozem soil by adding liming material the amount of uptaken potassium was decreasing, that is due to the antagonism between Ca- and K-ions. -
Response of sugar beet to different foliar fertilizers
127-136Views:437The yield and quality of the sugar beet are mainly determined by level crop production system; therefore the effects of foliar fertilization were studied. Our field trials were carried out in 2005 and 2006 in Hajdúböszörmény, at two experimental sites. In our trials the effects of Biomit Plussz, Fitohorm and Kelcare Cu (having high Cu content) as foliar fertilizers, as well as a fungicide with high sulphur content, Cosavet DF, were studied and
compared. Effects of treatments were studied in four replicates.
We took root samples at 4 week intervals, starting in August. The quality of root (sucrose, potassium, sodium and alfa-amino N content) was determined from filtrated beet broth, by an automatic beet laboratory system, called VENEMA. Leaf samples were taken three times in the growing season, element composition was measured by ICP-OES.
We found that the crop and the sugar yield were significantly influenced by the foliar treatments both of the two years. -
The significance of sour cherry in iron supplementation
101-104Views:406The iron concentration of ’Csengődi csokros’, ’Debreceni- and ’Érdi bőtermő’ , ‘Éva’, ’Kántorjánosi’ ,’Petri’ and the ’Újfehértói fürtös’ cultivars was determined by ICP-MS. Furthermore the Vitamin C, L-Malis acid and Citric acid concentration of samples were measured.
Our results show that large amount Fe2+ (average 20.5 mg kg-1) accumulates in the pulp of sour cherry. Besides, the concentration of Vitamin C, L-Malis acid, that increase the absorption of iron, are high. Based on these results, the sour cherry and the products of sour cherry play an important role in the forming of iron content in body.
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Foliar treatments of Sugar beet
55-59Views:383The yield and quality of the sugar beet are mainly determined by the plant production system, thus we studied the effect of mineral fertilization. Our field trials were carried out in 2005 and 2006 in Hajdúböszörmény, at two sites. We studied the effect of sulphur (Cosavet DF), copper (Kelcare Cu) and two foliar nutrients with high active agents. Treatments were replicated four times.
We took root and leaf samples at 4 week intervals, starting in August. The quality of root (sucrose, potassium, sodium and alfaamino N content) was determined from filtrated beet broth, by an automatic beet laboratory system, called VENEMA. Leaf samples were measured with ICP-OES.
We found that the crop and the sugar yield were significantly influenced by the foliar treatments.