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Investigation of Chromium(III)-Picolinate Adsorption on Some Soil Types
190-193Views:73In the experiment adsorption characteristics of different soil types (humic sand, meadow soil, leached chernozem and meadow solonec) was examined on the basis of adsorption isotherms for Cr(III)-picolinate. The Langmuir equation was used to describe the isotherms by which the amounts of metal ions actually and maximally adsorbed by the soils were determined concerning the given complex. A comparison was made among the organically bound Cr(III)-picolinate, an inorganic Cr(III) compound and a Cr(VI) form examined in a previous study. Based on the adsorption isotherms, adsorption capacity of the Cr(III)-picolinate was found 20 times smaller on sandy soil and 50 times smaller on the chernozem comparing to that of the inorganic Cr(III)-chloride, thus, the bio-availability of the chromium for the plants is 20 and 50 times higher in case of the given soil types. For the well-known toxic Cr(VI)-form, the adsorption was 2 times higher in case of sandy soil and 5 times higher for chernozem than in case of the organic Cr(III)-complex compound.
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SIM Samples Investigation by Statistical Methods
194-197Views:91The assessment of the present condition of the soil is very important, because the accession of the number of the European Union members is in the near future. This can be the base of the modern agrarian environmental management programme. The assessment must be objective, detailed and analyse the processes in the soil.
Respecting the above causes was decided to create an Environmental Information Monitoring System. This system consists of more parts. One of them is the Soil Information Monitoring System (SIM). This system started to work in 1992.
This system has two functions. Creating and actuation is obligatory from the international contracts, on the other hand the public SIM has very important role in the conservation of the soil.
The SIM territorial measuring grid consists of 1236 measuring points. These points are representatives. The distributions of the points by the types of soil attend the variety of the types of soil of the country.
The investigated elements in 6 types of soil were in our experiment (the group of scandium and the lanthanide series elements). There are 6 elements above the detection limit (Gadolinium, Neodymium, Praseodymium, Scandium, Samarium, Yttrium).
The Neodymium concentration is 2 times higher than the content of Gadolinium and Yttrium.
The Neodymium concentration is 4 times higher than the content of Praseodymium, Scandium and Samarium.
In the case of Dysprosium, Europium, Lutetium, Terbium, Ytterbium the concentrations were below 1 mg/kg.